If your looking for a diffrent desktop experiance the OS doesnt matter outside of if it has packages or not. You might want to try KDE plasma with custom themes if your not a fan of the way xfce works. Although xfce is also extreamly customizable in the way it works too if you take some time to read the docs
Currently switching my desktops from alpine to void just for the fun of it. Servers will always be alpine but void just feels right on the desktop!